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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Norie Momiyama,
Hiromi Torii,
Susumu Saito,
and Hisashi Yamamoto

Asymmetric Catalysis Special Feature Part I: O-nitroso aldol synthesis: Catalytic enantioselective route to α-aminooxy carbonyl compounds via enamine intermediate

PNAS 2004 101:5374-5378; published online before print April 5, 2004, doi:10.1073/pnas.0307785101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

David L. Hughes,
Guy C. Lloyd-Jones,
Shane W. Krska,
Laure Gouriou,
Veronique D. Bonnet,
Kevin Jack,
Yongkui Sun,
David J. Mathre,
and Robert A. Reamer

Asymmetric Catalysis Special Feature Part I: Mechanistic studies of the molybdenum-catalyzed asymmetric alkylation reaction

PNAS 2004 101:5379-5384; published online before print March 31, 2004, doi:10.1073/pnas.0306918101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Ilya D. Gridnev,
Masaya Yasutake,
Tsuneo Imamoto,
and Irina P. Beletskaya

Asymmetric Catalysis Special Feature Part I: Asymmetric hydrogenation of α,β-unsaturated phosphonates with Rh-BisP* and Rh-MiniPHOS catalysts: Scope and mechanism of the reaction

PNAS 2004 101:5385-5390; published online before print March 15, 2004, doi:10.1073/pnas.0306993101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Michael P. Doyle,
Marcela Valenzuela,
and Penglin Huang

Asymmetric Catalysis Special Feature Part I: Asymmetric hetero-Diels–Alder reaction catalyzed by dirhodium(II) carboxamidates

PNAS 2004 101:5391-5395; published online before print April 1, 2004, doi:10.1073/pnas.0307025101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Natasha Cheeseman,
Martin Fox,
Mark Jackson,
Ian C. Lennon,
and Graham Meek

Asymmetric Catalysis Special Feature Part I: An efficient, palladium-catalyzed, enantioselective synthesis of (2R)-3-butene-1,2-diol and its use in highly selective Heck reactions

PNAS 2004 101:5396-5399; published online before print February 11, 2004, doi:10.1073/pnas.0307047101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Kristina Hallman,
Anders Frölander,
Tebikie Wondimagegn,
Mats Svensson,
and Christina Moberg

Asymmetric Catalysis Special Feature Part I: OH–Pd(0) interaction as a stabilizing factor in palladium-catalyzed allylic alkylations

PNAS 2004 101:5400-5404; published online before print April 5, 2004, doi:10.1073/pnas.0307084101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Alexandre Côté,
Alessandro A. Boezio,
and André B. Charette

Asymmetric Catalysis Special Feature Part I: Catalytic asymmetric addition of diorganozinc reagents to N-phosphinoylalkylimines

PNAS 2004 101:5405-5410; published online before print April 2, 2004, doi:10.1073/pnas.0307096101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Zihao Hua,
Victor C. Vassar,
Hojae Choi,
and Iwao Ojima

Asymmetric Catalysis Special Feature Part I: New biphenol-based, fine-tunable monodentate phosphoramidite ligands for catalytic asymmetric transformations

PNAS 2004 101:5411-5416; published online before print March 12, 2004, doi:10.1073/pnas.0307101101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Ge Gao,
Ru-Gang Xie,
and Lin Pu

Asymmetric Catalysis Special Feature Part I: Highly enantioselective alkyne additions to aldehydes in the presence of 1,1′-bi-2-naphthol and hexamethylphosphoramide

PNAS 2004 101:5417-5420; published online before print March 16, 2004, doi:10.1073/pnas.0307136101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Brian M. Bocknack,
Long-Cheng Wang,
and Michael J. Krische

Asymmetric Catalysis Special Feature Part I: Desymmetrization of enone-diones via rhodium-catalyzed diastereo- and enantioselective tandem conjugate addition-aldol cyclization

PNAS 2004 101:5421-5424; published online before print March 15, 2004, doi:10.1073/pnas.0307120101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Hongmei Li,
Celina García,
and Patrick J. Walsh

Asymmetric Catalysis Special Feature Part I: Catalytic asymmetric addition of diphenylzinc to cyclic α,β-unsaturated ketones

PNAS 2004 101:5425-5427; published online before print April 5, 2004, doi:10.1073/pnas.0307119101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Clark R. Landis
and Thomas P. Clark

Asymmetric Catalysis Special Feature Part I: Solid-phase synthesis of chiral 3,4-diazaphospholanes and their application to catalytic asymmetric allylic alkylation

PNAS 2004 101:5428-5432; published online before print February 25, 2004, doi:10.1073/pnas.0307572100

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Yuhei Fukuta,
Takashi Ohshima,
Vijay Gnanadesikan,
Tomoyuki Shibuguchi,
Tetsuhiro Nemoto,
Takaya Kisugi,
Tatsufumi Okino,
and Masakatsu Shibasaki

Asymmetric Catalysis Special Feature Part I: Enantioselective syntheses and biological studies of aeruginosin 298-A and its analogs: Application of catalytic asymmetric phase-transfer reaction

PNAS 2004 101:5433-5438; published online before print March 2, 2004, doi:10.1073/pnas.0307154101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Scott E. Denmark
and Tommy Bui

Asymmetric Catalysis Special Feature Part I: Chiral phosphoramide-catalyzed, enantioselective, directed cross-aldol reactions of aldehydes

PNAS 2004 101:5439-5444; published online before print April 5, 2004, doi:10.1073/pnas.0307212101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Norihito Tokunaga,
Kazuhiro Yoshida,
and Tamio Hayashi

Asymmetric Catalysis Special Feature Part I: Mechanistic studies on the catalytic cycle of rhodium-catalyzed asymmetric 1,4-addition of aryltitanate reagents to α,β-unsaturated ketones

PNAS 2004 101:5445-5449; published online before print February 23, 2004, doi:10.1073/pnas.0307260101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

David M. Hodgson,
Tobias Brückl,
Rebecca Glen,
Agnès H. Labande,
Deborah A. Selden,
Alexander G. Dossetter,
and Alison J. Redgrave

Asymmetric Catalysis Special Feature Part I: Catalytic enantioselective intermolecular cycloadditions of 2-diazo-3,6-diketoester-derived carbonyl ylides with alkene dipolarophiles

PNAS 2004 101:5450-5454; published online before print March 22, 2004, doi:10.1073/pnas.0307274101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Mark Lautens
and Keith Fagnou

Asymmetric Catalysis Special Feature Part I: Rhodium-catalyzed asymmetric ring opening reactions of oxabicyclic alkenes: Catalyst and substrate studies leading to a mechanistic working model

PNAS 2004 101:5455-5460; published online before print April 5, 2004, doi:10.1073/pnas.0307271101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Michael Reggelin,
Sebastian Doerr,
Martin Klussmann,
Melanie Schultz,
and Michael Holbach

Asymmetric Catalysis Special Feature Part I: Helically chiral polymers: A class of ligands for asymmetric catalysis

PNAS 2004 101:5461-5466; published online before print March 30, 2004, doi:10.1073/pnas.0307443101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Varinder K. Aggarwal,
Jonathan Charmant,
Leo Dudin,
Marina Porcelloni,
and Jeffery Richardson

Asymmetric Catalysis Special Feature Part I: Effect of sulfide structure on enantioselectivity in catalytic asymmetric epoxidation of aldehydes: Mechanistic insights and implications

PNAS 2004 101:5467-5471; published online before print March 19, 2004, doi:10.1073/pnas.0307559101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Huw M. L. Davies
and Qihui Jin

Asymmetric Catalysis Special Feature Part I: Catalytic asymmetric reactions for organic synthesis: The combined C—H activation/Cope rearrangement

PNAS 2004 101:5472-5475; published online before print March 15, 2004, doi:10.1073/pnas.0307556101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry:

Shū Kobayashi,
Masaharu Ueno,
Susumu Saito,
Yumiko Mizuki,
Haruro Ishitani,
and Yasuhiro Yamashita

Asymmetric Catalysis Special Feature Part I: Air-stable, storable, and highly efficient chiral zirconium catalysts for enantioselective Mannich-type, aza Diels–Alder, aldol, and hetero Diels–Alder reactions

PNAS 2004 101:5476-5481; published online before print April 5, 2004, doi:10.1073/pnas.0307870101

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Asymmetric Catalysis Special Feature Part I - Research Articles - Physical Sciences - Chemistry - From the Cover: ASYMMETRIC CATALYSIS SPECIAL FEATURE PART I:

Joel F. Austin,
Sung-Gon Kim,
Christopher J. Sinz,
Wen-Jing Xiao,
and David W. C. MacMillan

From the Cover: Asymmetric Catalysis Special Feature Part I: Enantioselective organocatalytic construction of pyrroloindolines by a cascade addition–cyclization strategy: Synthesis of (–)-flustramine B

PNAS 2004 101:5482-5487; published online before print April 5, 2004, doi:10.1073/pnas.0308177101

FROM THE COVER

Coincidence detection enhances appropriate wiring of the nervous system

Silence of the genes

Inaugural Article: Biography of James L. Van Etten

Inaugural Article: Biography of Zhu Chen

Inaugural Article: Biography of Joseph S. Takahashi

Asymmetric Catalysis Special Feature Part I: Asymmetric Catalysis

Asymmetric Catalysis Special Feature Part I: Asymmetric catalysis: An enabling science

Asymmetric Catalysis Special Feature Part I: Toward efficient asymmetric hydrogenation: Architectural and functional engineering of chiral molecular catalysts

Asymmetric Catalysis Special Feature Part I: Catalytic asymmetric synthesis of all-carbon quaternary stereocenters

Asymmetric Catalysis Special Feature Part I: Asymmetric catalysis in complex target synthesis

Asymmetric Catalysis Special Feature Part I: O-nitroso aldol synthesis: Catalytic enantioselective route to α-aminooxy carbonyl compounds via enamine intermediate

Asymmetric Catalysis Special Feature Part I: Mechanistic studies of the molybdenum-catalyzed asymmetric alkylation reaction

Asymmetric Catalysis Special Feature Part I: Asymmetric hydrogenation of α,β-unsaturated phosphonates with Rh-BisP* and Rh-MiniPHOS catalysts: Scope and mechanism of the reaction

Asymmetric Catalysis Special Feature Part I: Asymmetric hetero-Diels–Alder reaction catalyzed by dirhodium(II) carboxamidates

Asymmetric Catalysis Special Feature Part I: An efficient, palladium-catalyzed, enantioselective synthesis of (2R)-3-butene-1,2-diol and its use in highly selective Heck reactions

Asymmetric Catalysis Special Feature Part I: OH–Pd(0) interaction as a stabilizing factor in palladium-catalyzed allylic alkylations

Asymmetric Catalysis Special Feature Part I: Catalytic asymmetric addition of diorganozinc reagents to N-phosphinoylalkylimines

Asymmetric Catalysis Special Feature Part I: New biphenol-based, fine-tunable monodentate phosphoramidite ligands for catalytic asymmetric transformations

Asymmetric Catalysis Special Feature Part I: Highly enantioselective alkyne additions to aldehydes in the presence of 1,1′-bi-2-naphthol and hexamethylphosphoramide

Asymmetric Catalysis Special Feature Part I: Desymmetrization of enone-diones via rhodium-catalyzed diastereo- and enantioselective tandem conjugate addition-aldol cyclization

Asymmetric Catalysis Special Feature Part I: Catalytic asymmetric addition of diphenylzinc to cyclic α,β-unsaturated ketones

Asymmetric Catalysis Special Feature Part I: Solid-phase synthesis of chiral 3,4-diazaphospholanes and their application to catalytic asymmetric allylic alkylation

Asymmetric Catalysis Special Feature Part I: Enantioselective syntheses and biological studies of aeruginosin 298-A and its analogs: Application of catalytic asymmetric phase-transfer reaction

Asymmetric Catalysis Special Feature Part I: Chiral phosphoramide-catalyzed, enantioselective, directed cross-aldol reactions of aldehydes

Asymmetric Catalysis Special Feature Part I: Mechanistic studies on the catalytic cycle of rhodium-catalyzed asymmetric 1,4-addition of aryltitanate reagents to α,β-unsaturated ketones

Asymmetric Catalysis Special Feature Part I: Catalytic enantioselective intermolecular cycloadditions of 2-diazo-3,6-diketoester-derived carbonyl ylides with alkene dipolarophiles

Asymmetric Catalysis Special Feature Part I: Rhodium-catalyzed asymmetric ring opening reactions of oxabicyclic alkenes: Catalyst and substrate studies leading to a mechanistic working model

Asymmetric Catalysis Special Feature Part I: Helically chiral polymers: A class of ligands for asymmetric catalysis

Asymmetric Catalysis Special Feature Part I: Effect of sulfide structure on enantioselectivity in catalytic asymmetric epoxidation of aldehydes: Mechanistic insights and implications

Asymmetric Catalysis Special Feature Part I: Catalytic asymmetric reactions for organic synthesis: The combined C—H activation/Cope rearrangement

Asymmetric Catalysis Special Feature Part I: Air-stable, storable, and highly efficient chiral zirconium catalysts for enantioselective Mannich-type, aza Diels–Alder, aldol, and hetero Diels–Alder reactions

From the Cover: Asymmetric Catalysis Special Feature Part I: Enantioselective organocatalytic construction of pyrroloindolines by a cascade addition–cyclization strategy: Synthesis of (–)-flustramine B

From the Cover: Asymmetric Catalysis Special Feature Part I: Enantioselective organocatalytic construction of pyrroloindolines by a cascade addition–cyclization strategy: Synthesis of (–)-flustramine B

Asymmetric Catalysis Special Feature Part I: O-nitroso aldol synthesis: Catalytic enantioselective route to α-aminooxy carbonyl compounds via enamine intermediate

Asymmetric Catalysis Special Feature Part I: Mechanistic studies of the molybdenum-catalyzed asymmetric alkylation reaction

Asymmetric Catalysis Special Feature Part I: Asymmetric hydrogenation of α,β-unsaturated phosphonates with Rh-BisP* and Rh-MiniPHOS catalysts: Scope and mechanism of the reaction

Asymmetric Catalysis Special Feature Part I: Asymmetric hetero-Diels–Alder reaction catalyzed by dirhodium(II) carboxamidates

Asymmetric Catalysis Special Feature Part I: An efficient, palladium-catalyzed, enantioselective synthesis of (2R)-3-butene-1,2-diol and its use in highly selective Heck reactions

Asymmetric Catalysis Special Feature Part I: OH–Pd(0) interaction as a stabilizing factor in palladium-catalyzed allylic alkylations

Asymmetric Catalysis Special Feature Part I: Catalytic asymmetric addition of diorganozinc reagents to N-phosphinoylalkylimines

Asymmetric Catalysis Special Feature Part I: New biphenol-based, fine-tunable monodentate phosphoramidite ligands for catalytic asymmetric transformations

Asymmetric Catalysis Special Feature Part I: Highly enantioselective alkyne additions to aldehydes in the presence of 1,1′-bi-2-naphthol and hexamethylphosphoramide

Asymmetric Catalysis Special Feature Part I: Desymmetrization of enone-diones via rhodium-catalyzed diastereo- and enantioselective tandem conjugate addition-aldol cyclization